Overview:
Chemical stabilizers (e.g., lime, cement, and geopolymers) are frequently used to improve the engineering properties of weak soils. The geochemical reactions between the stabilizer and soil minerals result in the formation of strength-enhancing pozzolanic products such as Calciumsilicate-hydrates (C-S-H). Modeling the complex geochemical reactions resulting in the formation of strength-enhancing products can provide valuable insights for evaluating the effectiveness of a stabilizer. For example, in a moisture-laden environment, C-S-H with a low Ca to Si ratio (Ca/Si~0.33) is more stable as compared to C-S-H with a high Ca to Si ratio (Ca/Si >1). The geochemical model can help determine the soil type and field conditions required to form a durable C-S-H. This project will develop a prototype computational model that can simulate the reaction between a chemical stabilizer and reactive soil minerals at different periods after stabilization. The focus is on evaluating conditions (e.g., pH, the reactivity of soil minerals, and other similar factors) favoring the formation of durable pozzolanic products (e.g., Ca/Si~0.66). The results of this study will also be used to provide recommendations during construction that can help achieve durable, stabilized soil materials
Funding agency: US-Army Engineering and Research Division